N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrO(x) under mild reaction conditions.
نویسندگان
چکیده
An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 88 شماره
صفحات -
تاریخ انتشار 2014